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產(chǎn)品基本信息
產(chǎn)品編號：D360500
產(chǎn)品名稱：(Diacetoxyiodo)benzene
產(chǎn)品CAS：3240-34-4
規(guī)格含量：50g
產(chǎn)品價(jià)格：面議
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產(chǎn)品詳細(xì)介紹
標(biāo)準(zhǔn)品編號:
D360500
名稱:
(Diacetoxyiodo)benzene
別名:
(Dihydroxyiodo)benzene; (Diacetoxyiodo)benzene; BAIB; Bis(acetato)phenyliodine; Bis(acetato-κO)phenyliodine; Diacetoxy(phenyl)iodine; Iodobenzene Diacetate; Iodophenyl Diacetate; Iodosobenzene Diacetate; Iodosylbenzene Diacetate; NSC 226375; NSC 23801; PIDA; Phenyliodine Diacetate; Phenyliodine(III) Diacetate; Phenyliodo Diacetate; Phenyliodonium Diacetate; Phenyliodoso Acetate; Phenyliodoso Diacetate; Phenyliodosyl Diacetate; [Bis(acetoxy)iodo]benzene; Iodosodiacetate Benzene;
CAS號:
3240-34-4
分子式:
C??H??IO?
外觀:
白色至白色固體
熔點(diǎn):
161-163°C
分子量:
322.1
儲存:
Amber Vial, -20°C Freezer, Under inert atmosphere
溶解性:
DMSO (Slightly), Ethyl Acetate (Slightly, Heated), Methanol (Slightly)
穩(wěn)定性:
Light and Moisture sensitive
種類:
Building Blocks; Miscellaneous;
應(yīng)用:
(Diacetoxyiodo)benzene is a hypervalent iodine reagent that is used in conjunction with catalytic amount of sodium azide in acetonitrile, which enables oxidative decarboxylation of 2-aryl carboxylic acid into the corresponding aldehydes, ketones and nitriles.
參考文獻(xiàn)
Telvekar, V.N., et al.: Synlett., 2778 (2012); Liu, W.B., et al.: Beilstein. J. Org. Chem., 8, 244 (2012);
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