產品基本信息
產品編號：B430370
產品名稱：2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene
產品CAS：98327-87-8
規(guī)格含量：25g
產品價格：面議
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產品詳細介紹
標準品編號:
B430370
名稱:
2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene
別名:
1,1'-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine]; [1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine]; (±)-BINAP; 2,2'-Bis(diphenylphosphanyl)-1,1'-binaphthyl; 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl; BINAP; [1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine]; rac-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl; rac-BINAP
CAS號:
98327-87-8
分子式:
C??H??P?
外觀：
白色至白色固體
熔點:
>200ºC (dec.)
分子量:
622.67
儲存:
Room Temperature, under inert atmosphere
溶解度:
Chloroform (Slightly, Sonicated), Dichloromethane (Slightly, Heated),
種類:
Building Blocks; Catalyst;
應用:
2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene is a powerful chiral auxiliary that is used as a homogeneous catalyst in some asymmetric chemical syntheses. 2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene is utilized for its high enantioselectivity and is used as a ligand to create coordination complexes.
文獻
DiBari, L., et al.: J. Am. Chem. Soc., 121, 7998 (1999); Hatano, M., et al.: J. Am. Chem. Soc., 130, 16858 (2008); Kitamura, M., et al.: Tetrahedron Lett., 32, 4163 (1991); Shimada, T., et al.: J. Org. Chem., 66, 8854 (2001)
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